POLITANO FABRIZIO
Artículos
Título:
Using experimental and computational approaches to probe an unusual carbon-carbon bond cleavage observed in the synthesis of benzimidazole: N -oxides
Autor/es:
POLITANO, FABRIZIO; SANDOVAL, ARTURO LEÓN; URANGA, JORGE G.; BUJÁN, ELBA I.; LEADBEATER, NICHOLAS E.
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Año: 2021 vol. 19 p. 208 - 208
ISSN:
1477-0520
Resumen:
xperimental and computational studies have been performed in order to investigate an unusual carbon-carbon bond cleavage that occurs in the preparation of certain benzimidazole N-oxides from anilines. The key factor determining the outcome of the reaction was found to be the substituents on the amine functionality of the aniline.